![]() |
![]() |
![]() |
![]() |
Общее | ![]() | ![]() |
![]() |
Новости | ![]() | ![]() |
![]() |
Студенту | ![]() | ![]() |
![]() |
Школьнику и абитуриенту | ![]() | ![]() |
![]() |
Учебные и научные материалы | ![]() | ![]() |
![]() |
Учебные карты | ![]() | ![]() |
![]() |
Энциклопедия GeoWiki | ![]() | ![]() |
![]() |
Форум | ![]() | ![]() |
![]() |
Журналы | ![]() | ![]() |
![]() |
Конференции | ![]() | ![]() |
||||||||||
![]() |
Authigenic carbonates associated with cold seeps provide valuable archives of changes in the long-term seepage activity. To investigate the role of shallow-buried hydrates on the seepage strength and fluid composition we analysed methane-derived carbonate precipitates from a high-flux hydrocarbon seepage area ("Batumi seep area") located on the south-eastern Black Sea slope in ca. 850 m. In a novel approach, we combined computerized X-ray tomography (CT) with mineralogical and isotope geochemical methods to get additional insights into the three-dimensional internal structure of the carbonate build-ups. X-ray diffractometry revealed the presence of two different authigenic carbonate phases, i.e. pure aragonitic rims associated with vital microbial mats and high-Mg calcite cementing the hemipelagic sediment. As indicated by the CT images, the initial sediment has been strongly deformed, first plastic then brittle, leading to brecciation of the progressively cemented sediment. The aragonitic rims on the other hand, represent a presumably recent carbonate growth phase since they cover the already deformed sediment. The stable oxygen isotope signature indicates that the high-Mg calcite cement incorporated pore water mixed with substantial hydrate water amounts. This points at a dominant role of high gas/fluid flux from decomposing gashydrates leadingtothe deformationandcementationof the overlyingsediment. Incontrast, the aragonitic rims do not showan influence of d18O-enriched hydratewater. The differences in d18O between the presumably recent aragonite precipitates and the older high-Mgcements suggest that periods of hydrate dissociation and vigorous fluid discharge alternated with times of hydrate stability and moderate fluid flow. These results indicate that shallow-buried gas hydrates are prone to episodic decompositionwith associated vigorous fluid flow. This might have a profound impact on the seafloor morphology resulting e.g. in the formation of carbonate pavements and pockmark-like structures but might also affect the local carbon cycle.
![]() |
||
119991, Российская Федерация, Москва, ГСП-1, Ленинские горы, Московский государственный университет имени М.В. Ломоносова, Геологический факультет, Телефон: (495)939-2970, Факс: (495)932-8889, E-mail: admin@geol.msu.ru |
||